To see the information for all drives at once you need to be in Details View (menu: View | Details). In all other views hover with the mouse over the drive icon to get the info in form of a tooltip.

If you choose a drive and display its Property sheet you can see a graphical display of the drive's space, but there is a faster way to see this for all drives: Right-click on the My Computer icon and choose Open. Now, as you move with the mouse over the drive icons, you will see a pie chart of the drive space on the left, along with capacity, free and used space data. (If this doesn't work, choose View | As Web page from the menu.)  

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